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LOCAL EQUILIBRIUM THEORY FOR THE DYNAMICS OF NONISOTHERMAL MIXED GAS ADSORPTION OF HIGH-CONCENTRATION COMPONENTS
Authors:Douglas D Frey
Affiliation:  a Department of Chemical Engineering, Yale University, New Haven, CT
Abstract:A local equilibrium theory for nonisothermal gas adsorption is developed which accounts for variations in interstitial gas velocity induced by adsorption. Also presented are expressions describing the entropy admissibility criterion. A solution is developed for a Riemann's problem involving adiabatic gas-phase adsorption where there is no inert diluent and where Langmuir isotherms apply.
Keywords:Adsorption dynamics  Gas adsorption  Adiabatic adsorption
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