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铝合金环保型钝化及其与漆膜的配套性能
引用本文:黄旋,苗毅,孙德成,杨承凤.铝合金环保型钝化及其与漆膜的配套性能[J].材料保护,2012,45(6):35-38,73.
作者姓名:黄旋  苗毅  孙德成  杨承凤
作者单位:1. 武汉材料保护研究所,湖北武汉,430030
2. 沈阳飞机工业集团有限公司,辽宁沈阳,110034
摘    要:为了进一步提高三价铬钝化膜的耐蚀性及其与漆膜的配套性能,以2024铝合金为基材,筛选出钝化液中的配位剂和缓蚀剂,并确定其工艺条件,开发了一种性能优良的环保型三价铬钝化液。结果表明:经硅溶胶封闭处理后的三价铬钝化膜结构致密,电化学性能优良,耐中性盐雾试验可达168h,其耐蚀性与Alodine1200六价铬钝化工艺相当;与环氧底漆和聚氨酯面漆的配套性好。

关 键 词:三价铬钝化  2024铝合金  配位剂  缓蚀剂  耐蚀性  漆膜配套性

Adaptability to Primer and Top Coating of Trivalent Chromium Passivation Coating on Aluminum Alloy Surface
HUANG Xuan,MIAO Yi,SUN De-cheng,YANG Cheng feng.Adaptability to Primer and Top Coating of Trivalent Chromium Passivation Coating on Aluminum Alloy Surface[J].Journal of Materials Protection,2012,45(6):35-38,73.
Authors:HUANG Xuan  MIAO Yi  SUN De-cheng  YANG Cheng feng
Affiliation:1(1.Wuhan Research Institute of Materials Protection,Wuhan 430030,China;2.Shenyang Aircraft Corporation,Shenyang 110034,China)
Abstract:A kind of trivalent Cr passivation fluid with environmental acceptability was formulated for 2024 Al alloy by properly screening complexing agent and inhibitor.The passivation conditions were established.The corrosion resistance and adaptability to primer and top coating of as-prepared trivalent Cr passivation coating were investigated.It was found that the trivalent Cr passivation coating had compact microstructure and excellent electrochemical performance.Namely,as-prepared trivalent Cr passivation coating was able to endure neutral salt spraying for 168 h,showing corrosion resistance comparable to that of hexavalent chromium passivation coating made from Alodine 1200.Besides,as-prepared trivalent Cr passivation coating had good adaptability to epoxy primer and polyurethane top coating.
Keywords:trivalent chromium passivation  2024 aluminum alloy  complexing agent  inhibitor  corrosion resistance  adaptability to primer and top coating
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