Nucleation curves of model natural gas hydrates on a quasi‐free water droplet |
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Authors: | Nobuo Maeda |
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Affiliation: | CSIRO Manufacturing Flagship, Ian Wark Laboratory, Clayton, VIC, Australia |
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Abstract: | Heterogeneous nucleation probability distributions of gas hydrates on a water droplet that was supported by inert and immiscible perfluorocarbon oil, perfluorodecalin is studied. The guest gas used was a mixture of 90 mol % methane and 10 mol % propane. The probability distribution was measured using a high pressure automated lag time apparatus under the guest gas pressure range of 6.7–12.5 MPa and the cooling rate range of 0.002–0.02 K/s. Nucleation curves were derived for unit area of water surface. The nucleation rate per unit area of water surface that was contained in a glass sample cell, which differed significantly from that on a quasi‐free water droplet, is also derived. It is concluded that the nucleation curves in the presence of a solid wall should be normalized to the unit length of the three‐phase line at which water, guest gas, and the solid wall meet. © 2015 American Institute of Chemical Engineers AIChE J, 61: 2611–2617, 2015 |
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Keywords: | nucleation hydrates nucleation curve nucleation rate gas hydrate natural gas |
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