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Effect of Ca on crystallization of Mg-based master alloy containing spherical quasicrystal
作者姓名:张金山  杜宏伟  卢斌峰  张焱  梁伟  许春香  陆风雷
作者单位:School of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
基金项目:国家自然科学基金;山西省自然科学基金
摘    要:Spherical icosahedral quasicrystalline phase (I-phase) was obtained by introducing Ca into Mg-Zn-Y alloy under conventional casting conditions. Due to the addition of Ca, Mg45Zn50Yn4.5Ca0.5 primary I-phase, which is thermodynamically stable and homogeneously distributed, was generated instead of decahedral quasicrystalline phase during the solidification process; the morphology of primary I-phase in the solidification microstructure changed from petal-like one (60-80 μm) to spherical one (≤ 15 μm). When the mass fraction of Ca reaches 0.05%, sphericalI-phase with the largest quantity, highest spheroidization rate and highest circular degree can be obtained. Meanwhile, due to the changed morphology and the decreased size of primaryI-phase, the hardness of Mg-Zn-Y-Ca master alloy is reduced. The application of spherical I-phase as particulate reinforced phase provides great opporttmities for the improvement of strength and toughness of magnesium alloys.

关 键 词:  镁基中间合金  球形准晶  结晶化
收稿时间:2006-09-15
修稿时间:2007-01-10

Effect of Ca on crystallization of Mg-based master alloy containing spherical quasicrystal
ZHANG Jin-shan,DU Hong-wei,LU Bin-feng,ZHANG Yan,LIANG Wei,XU Chun-xiang,LU Feng-lei.Effect of Ca on crystallization of Mg-based master alloy containing spherical quasicrystal[J].Transactions of Nonferrous Metals Society of China,2007,17(2):273-279.
Authors:ZHANG Jin-shan  DU Hong-wei  LU Bin-feng  ZHANG Yan  LIANG Wei  XU Chun-xiang  LU Feng-lei
Affiliation:School of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Abstract:Spherical icosahedral quasicrystalline phase (I-phase) was obtained by introducing Ca into Mg-Zn-Y alloy under conventional casting conditions. Due to the addition of Ca, Mg45Zn50Y4.5Ca0.5 primary I-phase, which is thermodynamically stable and homogeneously distributed, was generated instead of decahedral quasicrystalline phase during the solidification process: the morphology of primary I-phase in the solidification microstructure changed from petal-like one (60–80 μm) to spherical one (≤ 15 μm). When the mass fraction of Ca reaches 0.05%, spherical I-phase with the largest quantity, highest spheroidization rate and highest circular degree can be obtained. Meanwhile, due to the changed morphology and the decreased size of primary I-phase, the hardness of Mg-Zn-Y-Ca master alloy is reduced. The application of spherical I-phase as particulate reinforced phase provides great opportunities for the improvement of strength and toughness of magnesium alloys.
Keywords:magnesium alloy  Ca  spherical quasicrystal  crystallization  microstructure
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