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火焰原子吸收光谱法中表面活性剂对钼增感和抑制干扰作用的机理
引用本文:李枚枚,提淑华,崔力,王敬涛. 火焰原子吸收光谱法中表面活性剂对钼增感和抑制干扰作用的机理[J]. 冶金分析, 2000, 20(5): 1-1
作者姓名:李枚枚  提淑华  崔力  王敬涛
作者单位:沈阳大学师范学院!沈阳,110015,沈阳大学师范学院!沈阳,110015,沈阳大学师范学院!沈阳,110015,沈阳大学师范学院!沈阳,110015
摘    要:介绍了在火焰原子吸收光谱法中三乙醇胺及氯化十二烷基三甲基铵对钼的增感作用及消除干扰的能力。其机理是溶液表面张力的降低、雾化效率的提高、胶团化合物的形成及表面活性剂对钼 的富集作用。

关 键 词:火焰原子吸收光谱法  表面活性剂  增感  干扰    
修稿时间:1999-07-01

Mechanism of Enhancing Sensitivity and Eliminating Interference with Surfactant for the Determination of Molybdenum by Flame Atomic Absorption Spectrometry
LI Mei-mei,TI Shu-hua,CUI Li,WANG Jing-tao. Mechanism of Enhancing Sensitivity and Eliminating Interference with Surfactant for the Determination of Molybdenum by Flame Atomic Absorption Spectrometry[J]. Metallurgical Analysis, 2000, 20(5): 1-1
Authors:LI Mei-mei  TI Shu-hua  CUI Li  WANG Jing-tao
Abstract:It is reported that in the presence of anappropriate amount of triethanol amine (TEA) and dodecyltrimethyl-ammonium chloride(DTAC), the sensitivity for the FAAS determination of molybdenum and the ability toeliminate interference are remarkably enhanced. Its mechanism is to reduce the surfacetension of solution, to enhance the efficiency of nebulization, to generate glue group ofchemical combination and to concentrate molybdenum by surfactant.
Keywords:Flame atomic absorption spectrometry  Surfactant  Enhancing sensitivity  Interference  Molybdenum  
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