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| 功能化纳米碳酸钙母料的制备与表征 | |
| 引用本文： | 褚艳红,郭欢欢,张国宝,赵根锁,余守志,王经武.功能化纳米碳酸钙母料的制备与表征[J].化工矿物与加工,2008,37(3):17-19,22. |
| 作者姓名： | 褚艳红 郭欢欢 张国宝 赵根锁 余守志 王经武 |
| 作者单位： | 1. 郑州大学材料科学与工程学院,河南,郑州,450052;河南省分析测试中心,河南,郑州,450002 2. 郑州大学材料科学与工程学院,河南,郑州,450052 3. 河南省分析测试中心,河南,郑州,450002 |
| 摘 要： | 采用溶液聚合法分别制备了表面包覆有载体树脂、复合弹性体和环氧基团的P型和H型功能化纳米碳酸钙母料,并对两种母料的产率、化学结构和热性能进行了研究.结果表明:纳米CaCO3表面的复合包覆层含有弹性体、载体树脂和将来可与PET端基发生反应的环氧基团.由于载体树脂种类的差异,导致两种母料的热分解起始温度Tdo不同,其中,H型母料的热稳定性略高于P型母料,但是,不同的载体树脂对母料的产率没有明显影响. |
| 关 键 词： | 制备 功能化母料 纳米碳酸钙 热性能 |
| 文章编号： | 1008-7524（2008）03-0017-03 |
| 收稿时间： | 2007-09-06 |
| 修稿时间： | 2007年9月6日 |
Preparation and characterization of functional nanometer CaCO_3 master-batch |
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| CHU Yan-hong,GUO Huan-huan,ZHANG Guo-bao,ZHAO Gen-suo,YU Shou-zhi,WANG Jing-wu.Preparation and characterization of functional nanometer CaCO_3 master-batch[J].Industrial Minerals and Processing,2008,37(3):17-19,22. | |
| Authors: | CHU Yan-hong GUO Huan-huan ZHANG Guo-bao ZHAO Gen-suo YU Shou-zhi WANG Jing-wu |
| Affiliation: | CHU Yan-hong 1,2,GUO Huan-huan 1,ZHANG Guo-bao 2,ZHAO Gen-suo 2,YU Shou-zhi 2,WANG Jing-wu 1 (1.The College of Material Science , Engineering,Zhengzhou University,Zhengzhou Henan 450052,China,2.Henan Province Analysis , Testing Center,Zhengzhou Henan 450002,China) |
| Abstract: | H-type and P-type functional CaCO 3 master-batch coated with carrier resin,elastomer,and epoxy group were prepared by solution polymerization.The yield,chemical structures and thermal properties of the two kinds of master-batch were studied.The results showed that nanometer CaCO 3 particles were encapsulated with carrier resin,elastomer,and epoxy compound.H-type and P-type functional CaCO 3 master-batch had different pyrolysis onset temperature(T do) due to using different carrier resins.And thermal stabili... |
| Keywords: | preparation functional master-hatch nanometer calcium carbonate thermal properties |
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