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Ferroelectric properties of Bi3.4Ho0.6Ti3O12 thin films prepared by sol-gel method
Authors:ChengJu Fu  ZhiXiong Huang  Jie Li and DongYun Guo
Affiliation:(1) School of Materials Science and Technology, Wuhan University of Technology, Wuhan, 430070, China;(2) School of Mechanical Engineering, Chongqing University of Science and Technology, Chongqing, 400050, China;(3) Department of Physics, Wuhan University, Wuhan, 430072, China
Abstract:We have prepared the Ho-substituted bismuth titanate (Bi3.4Ho0.6Ti3O12, BHT) thin films on Pt/Ti/SiO2/Si substrates using sol-gel method. The crystal structure and morphology of the films were characterized using X-ray diffraction and atomic force microscopy. The BHT film shows a single phase of Bi-layered Aurivillius structure and dense microstructure. The 2Pr and 2Ec of the 600-nm-thick BHT film were 38.4 μC/cm2 and 376.1 kV/cm, respectively at applied electric field 500 kV/cm. The dielectric constant and dielectric loss are about 310 and 0.015 at a frequency of 1 MHz, respectively. The Pr value decreased to 93% of its pre-fatigue values after 4.46×109 switching cycles at 1 MHz frenquency, and the BHT film shows good insulating behavior according to the test of leakage current. Supported by the Hubei Province Natural Science Foundation (Grant No. 2007ABA309)
Keywords:Bi3  4Ho0  6Ti3O12 thin film  sol-gel method  ferroelectric property  fatigue  dielectric constant
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