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Oxidation of doped europium in BaMgAl10O17 by annealing studied by x‐ray‐absorption fine‐structure measurements
Authors:Ichiro Hirosawa  Tetsuo Honma  Kazuo Kato  Naoto Kijima  Yasuo Shimomura
Abstract:Abstract— We studied the influence of annealing in air on doped europium in BaMgAl10O17 by performing x‐ray absorption fine‐structure measurements. We determined the oxidation of doped divalent europium by annealing in air at over 500°C. The interatomic distance between the europium and the surrounding oxygen atoms was compressed by oxidation. It also appears that the oxidation process of europium is determined by the diffusion of oxygen into BaMgAl10O17.
Keywords:Phosphor  BAM  x‐ray absorption fine structure  oxidation  valence  local structure
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