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| 新颖Cyclen全同取代衍生物的合成 | |
| 引用本文： | 王爱健,席海涛,孙小强,张秀芹,陈强. 新颖Cyclen全同取代衍生物的合成[J]. 化学试剂, 2009, 31(8) |
| 作者姓名： | 王爱健 席海涛 孙小强 张秀芹 陈强 |
| 作者单位： | 1. 江苏工业学院,江苏精细石油化工重点实验室,江苏,常州,213164;南京大学,常州高新技术研究院,江苏,常州,213164 2. 江苏工业学院,江苏精细石油化工重点实验室,江苏,常州,213164 3. 南京大学,常州高新技术研究院,江苏,常州,213164 |
| 基金项目： | 国家自然科学基金资助项目，江苏省研究生科技创新基金 |
| 摘 要： | 以无水碳酸钾为缚酸剂,1,4,7,10-四氮杂环十二烷(Cyclen)和含溴亲电试剂为原料合成了几种新颖的Cyclen全同取代衍生物.与以三乙胺或二异丙基乙胺为缚酸剂相比,具有后操作简单、条件温和、产率高、环境友好等优点.产物经 1HNMR、MS表征了其结构. |
| 关 键 词： | 1,4,7,10-四氮杂环十二烷 衍生物 合成 |
Synthesis of novel cyclen derivatives |
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| WANG Ai-jian,XI Hai-tao,SUN Xiao-qiang,ZHANG Xiu-qin,CHEN Qiang. Synthesis of novel cyclen derivatives[J]. Chemical Reagents, 2009, 31(8) | |
| Authors: | WANG Ai-jian XI Hai-tao SUN Xiao-qiang ZHANG Xiu-qin CHEN Qiang |
| Affiliation: | 1.Key Laboratory of Fine Petrochemical Engineering;Jiangsu Polytechnic University;Changzhou 213164;China;2.Changzhou High Technology Research Institute;Nanjing University;China |
| Abstract: | A new easy-to-run route for synthesizing some novel pendant-armed benzene-containing cyclen derivatives was proposed.The titled compounds were synthesized by the reaction of 1,4,7,10-tetraazacyclododecane(cyclen)and the electrophilic reagent with potassium carbonate as the proton trapper and were characterized by MS and 1HNMR.The method features a lot of advantages,such as simplicity in operation,mild reaction conditions,high yield and environmental friendliness with the use of potassium carbonate instead o... |
| Keywords: | cyclen derivatives synthesis |
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