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可剥离型丙烯酸酯类压敏胶乳液的研制
引用本文:李爱葵,付新建,刘少兵,张华,周思凯. 可剥离型丙烯酸酯类压敏胶乳液的研制[J]. 粘接, 2010, 31(4): 58-61
作者姓名:李爱葵  付新建  刘少兵  张华  周思凯
作者单位:1. 中国石化扬子石化有限责任公司,江苏,南京,210048
2. 洛阳理工学院材料科学与工程系,河南,洛阳,471023
摘    要:以丙烯酸酯类为主要原料,以烯丙基烷基磺基琥珀酸双酯钠盐M10-S为反应型乳化剂,采用乳液聚合方法制备了一种可剥离型压敏胶乳液。探讨了N-羟甲基丙烯酰胺(NAM)、M10-S、增塑剂及基材对压敏胶性能的影响。结果表明,当NAM用量为总单体质量2.0%,M10-S为单体总质量0.6%,用总乳液质量20%的邻苯二甲酸二辛酯(DoP)为增塑剂,PP或不锈钢为基材时压敏胶具有较好的可剥离性及综合性能。

关 键 词:反应型乳化剂  乳液聚合  可剥离  压敏胶

Preparation of removable water-borne acrylate pressure-sensitive emulsion adhesive
LI Ai-kui,FU Xin-jian,LIU Shao-bing,ZHANG Hua,ZHOU Si-kai. Preparation of removable water-borne acrylate pressure-sensitive emulsion adhesive[J]. Adhesion in China, 2010, 31(4): 58-61
Authors:LI Ai-kui  FU Xin-jian  LIU Shao-bing  ZHANG Hua  ZHOU Si-kai
Affiliation:2 (1.Sinopec Yangzi Petrochemical Company Ltd., Nanjing, Jiangsu 210048, China; 2.Department of Materials Engineering, Luoyang Institute of Science and Technology, Luoyang, Henan 471003,China )
Abstract:The removable water-borne pressure-sensitive emulsion adhesive was prepared by seed emulsion polymerization with acrylates as the main monomers. The effects of N-methylol acrylamide(NAM), polymeriable emulsifer (M10-S), plasticizer and substrates on the properties of adhesive were investigated. The results indicated that the adhesive is removable and has optimal properties when the weight ratio of NAM and total monomers is 2 : 100, the weight ratio of M10-S and total monomers is 0.6 : 100, the weight ratio of plasticizer ( di-n-butyl phthalate ) and latex is 2.0% and the substrate is polypropylene(PP) or stainless steel.
Keywords:polymerizable emulsifier  emulsion polymerization  removable  pressure sensitive adhesive
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