| 四嗪类高氮含能材料研究进展 |
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| 引用本文： | 徐松林,阳世清,王云鹏.四嗪类高氮含能材料研究进展[J].化学推进剂与高分子材料,2007,5(1):14-19. |
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| 作者姓名： | 徐松林 阳世清 王云鹏 |
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| 作者单位： | 国防科技大学航天与材料工程学院,湖南长沙,410073;国防科技大学航天与材料工程学院,湖南长沙,410073;国防科技大学航天与材料工程学院,湖南长沙,410073 |
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| 基金项目： | 国家自然科学基金--中国工程物理研究院"NASF"联合基金
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火炸药武器装备预研基金 |
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| 摘 要： | 四嗪环是一种含氮质量分数达68.3%的六元氮杂环含能基团,是设计高能钝感含能材料中非常有效的结构单元;四嗪类高氮含能材料也是近年来国内外研究和报道较多的一种新型含能材料,部分具有生成焓高、热稳定性好和感度较低等特点。介绍了1,2,4,5-四嗪、1,2,3,4-四嗪和1,2,3,5-四嗪3大类四嗪环,并对几种四嗪类高氮含能化合物的合成、性能及其在含能材料中的应用研究进展进行了详细论述。
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| 关 键 词： | 含能材料 四嗪 合成 性能 综述 |
| 文章编号： | 1672-2191（2007）01-0014-06 |
| 修稿时间： | 2006-09-27 |
Research Advances in High-Nitrogen Energetic Materials Derived from Tetrazine |
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| XU Song-lin,YANG Shi-qing,WANG Yun-peng.Research Advances in High-Nitrogen Energetic Materials Derived from Tetrazine[J].Chemical Propellants & Polymeric Materials,2007,5(1):14-19. |
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| Authors: | XU Song-lin YANG Shi-qing WANG Yun-peng |
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| Affiliation: | College of Aeronautic and Material Engineering, National University of Defense Teehnology, ChangSha 410073,China |
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| Abstract: | Tetrazine ring is an energetic nitrogen hexa-heterocyclic group with nitrogen mass fraction of 68.3%,so it is a very effective structure unit in the design of high energetic,insensitive materials.The tetrazine high-nitrogen energetic materials are new kinds of ones researched and reported widely at home and abroad in recent years.The part of them possesses high enthalpy of formation,good thermal stability,lower sensitivity and so on.Three kinds of tetrazines: 1,2,4,5-tetrazine, 1,2,3,4-tetrazine and 1,2,3,5-tetrazine are introduced.The synthesis,properties of several high-nitrogen energetic compounds derived from tetrazines and the research advances on their applications as energetic materials are reviewed in detail. |
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| Keywords: | energetic material tetrazine synthesis performance review |
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