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助剂对抗黄变鞋用热塑性聚氨酯弹性体的影响研究
引用本文:吴炳峰,唐亚夫,詹中贤,牛杰峰,张应超.助剂对抗黄变鞋用热塑性聚氨酯弹性体的影响研究[J].化学推进剂与高分子材料,2007,5(3):30-32.
作者姓名:吴炳峰  唐亚夫  詹中贤  牛杰峰  张应超
作者单位:洛阳吉明化工有限公司,河南,洛阳,471012
摘    要:采用一步法合成了抗黄变鞋用热塑性聚氨酯弹性体,研究了助剂对抗黄变鞋用热塑性聚氨酯弹性体的影响。结果表明:添加适量助剂可提高鞋用热塑性聚氨酯弹性体的抗黄变性能,并能有效延缓鞋用热塑性聚氨酯弹性体的光老化速度,而对其他性能影响极小。当热塑性聚氨酯(TPU)的助剂添加量为聚酯二元醇质量的1.5%,紫外线吸收剂、自由基捕获剂、抗氧剂质量比为4:2:1时,TPU的综合性能最佳。

关 键 词:抗黄变  聚氨酯弹性体  助剂
文章编号:1672-2191(2007)03-0030-03
修稿时间:2007-02-15

Study on Effects of Assistant on Thermoplastic Polyurethane Elastomer With Resistance to Yellowing for Shoe Making
WU Bing-feng,TANG Ya-fu,ZHAN Zhong-xian,NIU Jie-feng,ZHANG Ying-chao.Study on Effects of Assistant on Thermoplastic Polyurethane Elastomer With Resistance to Yellowing for Shoe Making[J].Chemical Propellants & Polymeric Materials,2007,5(3):30-32.
Authors:WU Bing-feng  TANG Ya-fu  ZHAN Zhong-xian  NIU Jie-feng  ZHANG Ying-chao
Affiliation:Luoyang Jiming Chemical Industry Co. Ltd, Luoyang 471012, China
Abstract:The thermoplastic polyurethane elastomer with resistance to yellowing for shoe making was synthesized by using one-step method.The effect of assistant was studied.The results show that proper-content assistant can improve the resistance to yellowing of the thermoplastic polyurethane elastomer,and decrease their speed of light aging,but has a little influence on other performance of the elastomer.Thermoplastic polyurethane(TPU) has the best properties when assistant mass fraction is 1.5% based on polyester diol mass,m(UV absorbing agent): m(free radical capturing agent): m(antioxidant) is 4:2:1.
Keywords:resistance to yellowing  polyurethane elastomer  assistant
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