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Adsorption of benzoic acid by CTAB exchanged montmorillonite
Authors:Liang-Guo Yan  Jin Wang  Hai-Qin Yu  Qin Wei  Bin Du  Xiao-Quan Shan
Affiliation:aState Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China;bSchool of Chemistry and Chemical Engineering, Jinan University, Jinan 250022, China
Abstract:This paper reports the adsorption of benzoic acid from water on cetyl trimethylammonium exchanged montmorillonite (CTAB-montmorillonite). Important factors are the adsorbent concentration, ionic strength, equilibrium time and pH. The largest adsorption is at pH 9. The adsorption kinetics data fitted the pseudo-second-order equation. The adsorption isotherms at different pH were linear indicating a partition mechanism. Up to about 61% of the dissolved benzoic acid was adsorbed by CTAB-montmorillonite. These results indicate that CTAB-montmorillonite is a potential adsorbent for benzoic acid.
Keywords:Organo-montmorillonite  Adsorption  Benzoic acid  Adsorption kinetics
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