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高温钎焊立方氮化硼界面微结构
引用本文:丁文锋,徐九华,卢金斌,傅玉灿,XIAOBing,XUHong-jnn.高温钎焊立方氮化硼界面微结构[J].焊接学报,2004,25(5):29-32.
作者姓名:丁文锋  徐九华  卢金斌  傅玉灿  XIAOBing  XUHong-jnn
作者单位:南京航空航天大学,机电学院,南京,210016
基金项目:国家自然科学基金资助项目 ( 5 0 175 0 5 2 )
摘    要:以Ag-Cu-Ti合金为钎料采用真空钎焊的方法在优化的钎焊温度和时间下,实现了立方氮化硼(CBN)与砂轮基体的牢固连接。运用扫描电镜(SEM)、X射线能谱仪(EDS)及X射线粉末衍射仪(XRD)对连接界面的微观组织以及CBN表面生成物的三维形貌、化学成分、物相结构进行了综合分析。结果表明,钎料中的元素Ti向CBN表面扩散富集,生成了针状TiB2和TiN,在磨粒与钎料界面形成化学冶金结合,这是CBN与Ag-Cu-Ti钎料间有良好浸润性和高结合强度的主要原因。磨削对比试验表明钎焊CBN砂轮比电镀CBN砂轮具有更高的磨粒把持强度。

关 键 词:钎焊  立方氮化硼  Ag-Cu-Ti钎料  氮化钛  硼化钛
文章编号:0253-360X(2004)05-29-04
收稿时间:2003/11/5 0:00:00

Microstructure of high temperature brazing cubic boron hitride grits
DING Wen-feng,XU Jiu-hu,LU Jin-bin,FU Yu-can,XIAO Bing and XU Hong-jnn.Microstructure of high temperature brazing cubic boron hitride grits[J].Transactions of The China Welding Institution,2004,25(5):29-32.
Authors:DING Wen-feng  XU Jiu-hu  LU Jin-bin  FU Yu-can  XIAO Bing and XU Hong-jnn
Affiliation:College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China,College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China,College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China,College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China,College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China and College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
Abstract:In order to develop new generation monolayer brazed CBN ( cubic boron nitride) grinding wheels, Ag-Cu-Ti active filler alloy was utilized to braze CBN grits to steel substrate in vacuum furnace. The microstructure and the element distribution of the joining interface, as well the topography and the phase structure of the compounds on the surface of brazed CBN grits, were analyzed by scanning electron microscope, energy dispersion spectrometer and X-ray diffraction. The results show that Ti in the filler alloy transferred preferentially to the surface of the CBN grit to form a layer of needle-like Ti-nitride and Ti-boride compounds by the interaction reaction between Ti and N and B at high temperature. Thus, the chemical metallurgic joining has been formed in the interface between CBN grits and Ag-Cu-Ti alloys. Finally comparative grinding tests were performed with monolayer brazed CBN grinding wheels and electroplated ones, and the result indicates that the brazed wheels showed higher joining strength to the CBN grits than the latter.
Keywords:brazing  cubic boron nitride  Ag-Cu-Ti brazing filler metal  Ti-nitride  Ti-boride
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