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Uniform Magnetic Chains of Hollow Cobalt Mesospheres from One‐Pot Synthesis and Their Assembly in Solution
Authors:L. Guo  F. Liang  X. Wen  S. Yang  L. He  W. Zheng  C. Chen  Q. Zhong
Affiliation:1. School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, 100083 Beijing, P.R. China;2. Department of Chemistry, Hong Kong University of Science and Technology, Kowloon, Hong Kong, P.R. China;3. Department of Physics, Peking University, 100871 Beijing, P.R. China
Abstract:Magnetic chains up to 10 μm in length formed of hollow cobalt mesospheres (480–850 nm) with a 60 nm thick shell are synthesized by a new soft‐assembly protocol. The obtained chains show a saturation magnetization of 37.5 emu g–1, a remnant magnetization of 1.55 emu g–1, and a coercivity of ca. 66 Oe at 300 K. A possible mechanism for the formation of the chainlike hollow structures is proposed.
Keywords:Hollow materials  Magnetic materials  Self‐assembly  Solution processing
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