Enhanced properties of innovative laponite‐filled waterborne acrylic resin dispersions

In view of the possible future applications of waterborne automotive coatings, acrylic‐based nanocomposite dispersions were investigated by the simple mixing of aqueous laponite nanoparticle dispersions with acrylic resin dispersions. The mechanical, flow, and leveling properties of waterborne nanocomposite dispersion formulations containing increasing concentrations of silicate and nonvolatile components (nvc) in the acrylic dispersions were investigated. The results obtained were related to the morphological information obtained from transmission electron microscopy and wide‐angle X‐ray scattering measurements in liquid suspension or on the cured films. At low synthetic silicate loading when flow, leveling, and appearance properties were still acceptable for processing and application, a large increase in the modulus of the cured coating films was observed, which was a result of the special morphology of the laponite‐rich regions of the cured film. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 687–697, 2007