| 乙烯基三甲基硅烷等离子体聚合反应历程 |
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| 引用本文： | 林晓,颜文革.乙烯基三甲基硅烷等离子体聚合反应历程[J].辐射研究与辐射工艺学报,1992,10(4):211-213. |
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| 作者姓名： | 林晓 颜文革 |
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| 作者单位： | 中国科学院长春应用化学研究所 长春130022
(林晓，颜文革，季怡萍，陈捷)，中国科学院长春应用化学研究所 长春130022(徐纪平) |
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| 摘 要： | 应用色谱—质谱(GC-MS)及裂解色谱-质谱(PGC-MS)测定了乙烯基三甲基硅烷等离子体聚合反应中的气体冷凝物及聚合物,研究推导了等离子体聚合反应历程。单体在气相中被电子撞击,然后扩散到基底,在基底发生链增长和链终止反应。
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| 关 键 词： | 等离子体聚合 硅烷 聚合 VTMS |
THE MECHANISM OF THE PLASMA POLYMERIZATION OF VINYLTRIMETHYLSILANE |
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| Lin Xiao,Yan Wenge,Ji Yiping,Chen Jie,Xu Jiping Changchun Institute of Applied Chemistry,Academia Sinica,Changchun.THE MECHANISM OF THE PLASMA POLYMERIZATION OF VINYLTRIMETHYLSILANE[J].Journal of Radiation Research and Radiation Processing,1992,10(4):211-213. |
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| Authors: | Lin Xiao Yan Wenge Ji Yiping Chen Jie Xu Jiping Changchun Institute of Applied Chemistry Academia Sinica Changchun |
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| Affiliation: | Lin Xiao,Yan Wenge,Ji Yiping,Chen Jie,Xu Jiping Changchun Institute of Applied Chemistry,Academia Sinica,Changchun 130022 |
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| Abstract: | The gas condensates and polymers from plasma polymerization ofYTMS in glow discharge were analyzed by means of GC-MS and PGC-MS, respecti-vely. From the experimental results the reaction mechanism of polymerization of VTMSwas deduced. Monomers were activated in the gas phase by electron bombardment andsubsequently diffused to the substrate where they propagated and terminated. |
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| Keywords: | Plasma polymerization Vinyltrimethylsilane Polymerization mechanism Chromatography Mass spectrography |
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