Studies on synergistic solvent extraction of rare earth elements from nitrate medium by mixtures of 8-hydroxyquinoline with Cyanex 301 or Cyanex 302 |
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Authors: | TIAN Miaomiao JIA Qiong LIAO Wuping |
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Affiliation: | [1]College of Chemistry, Jilin University, Changchun 130012, China [2]State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China |
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Abstract: | Synergistic solvent extraction of rare earth elements (REEs) from nitrate medium was investigated with mixtures of 8-hydroxyquinoline (HQ) and acidic organophosphorus extractants, bis(2,4,4-trimethylpentyl) dithiophosphinic acid (Cyanex 301) and bis(2,4,4-trimethylpentyl) monothiophosphinic acid (Cyanex 302). The extraction behavior of Cyanex 301/Cyanex 302 and their binary mixtures with HQ towards several lanthanoids (La, Nd, Sm, Tb, Ho, Tm) and yttrium (Y) was investigated. The separation ability of REEs was studied according to the various extraction effects. The extraction mechanisms for yttrium were studied with the methods of slope analysis and constant moles in the synergistic systems. The extracted compounds, the equilibrium constants, and thermodynamic functions were also determined. |
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Keywords: | extraction rare earth elements 8-hydroxyquinoline Cyanex 301 Cyanex 302 |
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