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Thermodynamic analysis of the formation of In-situ reinforced phases in cast Al-4.5Cu alloy
Authors:Yanfeng Liang  Jing’en Zhou  Shengquan Dong  Tong Yang
Affiliation:(1) State Key Laboratory for Mechanical Behavior of Materials, School of Materials Engineering, Xi’an Jiaotong University, Xi’an, 710049, China;(2) School of Materials & Chemical Engineering, Xi’an Technological University, Xi’an, 710032, China
Abstract:The thermodynamic analysis of the formation of in-situ reinforced phases in (TiB2+Al3Ti)/Al-4.5Cu composites prepared by mixed salts reaction was conducted, and heat changes of mixed salts system were analyzed by differential thermal analysis(DTA).The results show that although TiB2 possesses the strongest formation ability in Al-Ti-B ternary system, [Ti] is relatively excessive in the in-situ reaction and it combines with Al to form Al3Ti phase. The reinforced phases are TiB2 and Al3Ti in the produced composites due to the reaction taking place to form reinforced phase with the addition of mixed salts into Al-4.5Cu melt between 900 °C and 1 032 °C.
Keywords:in-situ composites  thermodynamic, TiB2   Al3Ti
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