Organosilicon Derivatives of Buckminsterfullerene (C60): First Preparation of A Fullerene Silirane |
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| Authors: | Takeshi Akasaka Wataru Ando Kaoru Kobayashi Shigeru Nagase |
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| Affiliation: | a Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki, Japanb Department of Chemistry, Faculty of Education, Yokohama National University, Yokohama, Japan |
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| Abstract: | C60 reacts with photochemically generated bis(2,6-diisopropylphenyl)silylene (1) to give adducts, 2-4, as the isolable products. Spectroscopic analysis and theoretical investigation strongly support the silirane structure 2a, and not the isomeric 1,6-silamethano[10]annulene 2b. |
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