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熔盐电解法制备钨铜合金粉
引用本文:肖志华,廖春发,王旭. 熔盐电解法制备钨铜合金粉[J]. 有色金属(冶炼部分), 2013, 0(4): 49-52
作者姓名:肖志华  廖春发  王旭
作者单位:江西理工大学应用科学学院,江西赣州,341000
基金项目:国家自然科学基金资助项目(51074081)
摘    要:在NaCl-KCl-Na2WO4-CuO体系中采用熔盐电解法直接制取钨铜合金粉,并对产物进行了XRD、SEM及EDS分析。结果表明,在780~800℃电解、阴极电流密度106~133mA/cm2、电解时间3~4h、电压2.2~3.2V的条件下,可以得到纯度99%以上、平均粒度0.91μm的钨铜合金粉末,各项指标基本达到了工业上烧结钨铜合金的要求。

关 键 词:钨酸钠  氧化铜  熔盐电解  钨铜粉
收稿时间:2012-10-08
修稿时间:2012-10-21

Preparation of W-Cu Alloy Powder with Molten Salt Electrolysis Process
XIAO Zhi-hu,LIAO Chun-fa and WANG Xu. Preparation of W-Cu Alloy Powder with Molten Salt Electrolysis Process[J]. Nonferrous Metals(Extractive Metallurgy), 2013, 0(4): 49-52
Authors:XIAO Zhi-hu  LIAO Chun-fa  WANG Xu
Affiliation:College of Applied Science,Jiangxi University of Science and Technology,Ganzhou Jiangxi 341000 China,,
Abstract:Tungsten copper alloy powder was directly prepared in NaCl-KCl-Na2WO4-CuO system with molten salt electrolysis.The cathode electrolysis products were analyzed by XRD,SEM and EDS.The results show that copper tungsten alloy powder with purity of above 99% and average particle size of 0.91 μm is obtained under the reaction conditions including electrolytic temperature of 740~820 ℃,cathode current density of 106~133 mA/cm2,electrolysis time of 1.5~3.5 h,cell voltage of 2.2~3.2 V.The product reaches the manufacture requirement of sintering tungsten copper alloy in industry.
Keywords:sodium tungstate   copper oxide   molten salt electrolysis   tungsten copper alloy powder
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