Skeletal Isomerization of Linear Butenes on Boron Promoted Ferrierite: Effect of the Catalyst Preparation Technique |
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Authors: | Raúl A Comelli |
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Affiliation: | (1) Instituto de Investigaciones en Catálisis y Petroquímica—INCAPE, (FIQ-UNL, CONICET), Santiago del Estero 2654, S3000AOJ Santa Fe, Argentina |
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Abstract: | Potassium and acid ferrierites were impregnated with boron species by wet and incipient wetness techniques. All samples display
a medium-intensity band at 3,450–3,470 cm−1 associated to Si−OH···O groups corresponding to boron-containing units. The 1,398–1,404 cm−1 band assigned to the B–O stretching in BO3 units does not appear on boron–potassium–ferrierite prepared by wet impregnation. Catalytic performance during the linear
butene skeletal isomerization was measured. At 300 °C, boron impregnated by incipient wetness technique on acid ferrierite
reduces both linear butene conversion at a short time and isobutene yield in all time range. Boron–potassium–ferrierite prepared
by wet impregnation has a suitable acidity to promote isobutene production. At 450 °C, this sample shows the best performance,
being the isobutene yield 1.7 times higher than the acid-ferrierite one and reaching the highest isobutene selectivity (92%).
This performance is maintained with time. Both isobutene yield and by-product distribution are strongly affected by temperature;
dimer intermediates are formed. Finally, both kinds of hydroxyl groups corresponding to 3,466 and 3,635 cm−1 bands influence the isobutene production whereas BO3 sites are inactive for this reaction. |
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Keywords: | Boron– ferrierite Isobutene Skeletal isomerization Wet impregnation |
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