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Co3O4/g-C3N4复合光催化剂降解罗丹明B的研究
引用本文:刘莛予,宫懿桐,赵锦,王敏. Co3O4/g-C3N4复合光催化剂降解罗丹明B的研究[J]. 工业水处理, 2020, 0(2): 92-95
作者姓名:刘莛予  宫懿桐  赵锦  王敏
作者单位:沈阳市第二中学;东北大学机械工程及自动化学院
摘    要:为提高石墨相氮化碳(g-C3N4)的光催化性能,采用3D花状ZIF-Co与g-C3N4混合热处理的方法制备了3D花状Co3O4/g-C3N4复合光催化剂,并将其用于光催化降解罗丹明B模拟染料废水。结果表明:当ZIF-Co与g-C3N4的质量比为5%时,制备的Co3O4/g-C3N4的光催化性能最佳,在可见光下照射30 min,其对罗丹明B的降解率可达90%以上,且该催化剂的重复稳定性好。在降解罗丹明B的过程中活性基团的作用顺序为·O2->h+>·OH。

关 键 词:石墨相氮化碳  四氧化三钴  3D花状结构  光催化  罗丹明B

Study on the degradation of Rhodamine B by Co3O4/g-C3N4 composite photocatalyst
Liu Tingyu,Gong Yitong,Zhao Jin,Wang Min. Study on the degradation of Rhodamine B by Co3O4/g-C3N4 composite photocatalyst[J]. Industrial Water Treatment, 2020, 0(2): 92-95
Authors:Liu Tingyu  Gong Yitong  Zhao Jin  Wang Min
Affiliation:(The Shenyang No.2 High School,Shenyang 110011,China;School of Mechanical Engineering and Automation,Northeastern University,Shenyang 110189,China)
Abstract:To further improve the photocatalytic activity of g-C3N4,3D flower-like Co3O4/g-C3N4 were prepared via calcining the mixture of 3D flower-like ZIF-Co and g-C3N4.The prepared composite photocatalyst was used for the degradation of Rhodamine B(RhB)simulated wastewater.The results showed that above 90%of RhB can be removed in 30 min under visible light irradiation by the Co3O4/g-C3N4,when the mass ratio of ZIF-Co to g-C3N4 was 5%,which exhibited the best photocatalytic performance.In addition,the catalysts showed good stability.Besides,the role of radicals in RhB degradation followed the sequence:·O2->h+>·OH.
Keywords:g-C3N4  Co3O4  3D flower-like structure  photocatalysis  RhB
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