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Shape Selective Chemistries with Modified Mordenite Zeolites |
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| Authors: | Juan M. Garcés Michael M. Olken G. John Lee Garry R. Meima Pierre A. Jacobs Johan A. Martens |
| Affiliation: | (1) The Dow Chemical Company, Midland, MI 48640, USA;(2) JMG LLC, 1106 W. Sugnet Rd, Midland, MI 48640, USA;(3) Dow Chemical, Chemistry & Catalysis R&D, 1776 bldg, Midland, MI 48674, USA;(4) Dow Benelux N.V., Chemistry & Catalysis R&D, P.O. Box 48, 4530 Terneuzen, The Netherlands;(5) Laboratorium voor Oppervlaktechemie, Katholieke Universitat Leuven, Kardinaal Mercierlaan 92, 3030 Leuven, Belgium |
| Abstract: | This is a review of work carried at Dow Chemical on the design and characterization of novel mordenite catalysts with a unique micro and meso-porous structure characterized by a variety of methods including, TEM, BET surface area and pore size distribution, and n-decane hydro-conversion. The catalytic performance of these catalysts in shape selective reactions is illustrated with results from n-decane hydro-conversion and applications to alkylation and trans-alkylation reactions of mono and polynuclear aromatic hydrocarbons and other chemistries. Juan M. Garcés and G. John Lee both retired from The Dow Chemical Company. |
| Keywords: | Mordenite 3 DDM catalyst Mesoporosity Bifunctional hydro-conversion of n-decane Alkylation Trans-alkylation mono Polynuclear aromatics |
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