| 纳米蒙脱土插层聚合改性环氧树脂 |
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| 引用本文： | 李成吾,张天罡,刘艳辉,左继成,于柱.纳米蒙脱土插层聚合改性环氧树脂[J].化学与粘合,2011,33(1):15-17,26. |
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| 作者姓名： | 李成吾 张天罡 刘艳辉 左继成 于柱 |
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| 作者单位： | 李成吾,刘艳辉,左继成,于柱,LI Cheng-wu,LIU Yan-hui,ZUO Ji-cheng,YU Zhu(沈阳理工大学,材料科学与工程学院,辽宁,沈阳,110168);张天罡,ZHANG Tian-gang(沈阳桐赫日化有限公司,辽宁,沈阳,110044) |
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| 摘 要： | 以纳米蒙脱土为原料,采用插层聚合法制备了改性增韧环氧树脂.通过正交实验考查了混合时间、混合温度、蒙脱土类型、蒙脱土含量对改性环氧树脂断裂伸长率的影响.实验结果表明混合时间对改性环氧树脂的断裂伸长率影响最大,当混合时间为2h,混合温度为70℃,采用DK1类型的蒙脱土,添加量为2%时,制备的改性环氧树脂断裂伸长率为12.1...
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| 关 键 词： | 环氧树脂 纳米蒙脱土 插层聚合 增韧 |
Study on Modification of Epoxy Resin by Intercalation Polymerization Method with Using Nano Montmorillonite as Raw Materials |
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| LI Cheng-wu,ZHANG Tian-gang,LIU Yan-hui,ZUO Ji-cheng , YU Zhu.Study on Modification of Epoxy Resin by Intercalation Polymerization Method with Using Nano Montmorillonite as Raw Materials[J].Chemistry and Adhesion,2011,33(1):15-17,26. |
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| Authors: | LI Cheng-wu ZHANG Tian-gang LIU Yan-hui ZUO Ji-cheng YU Zhu |
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| Affiliation: | LI Cheng-wu1,ZHANG Tian-gang2,LIU Yan-hui1,ZUO Ji-cheng1 and YU Zhu1(1.College of Material Science and Engineering,Shenyang Ligong University,Shenyang 110168,China,2.Shenyang Tonghe Chemical Co.,Ltd.,Shenyang 110044,China) |
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| Abstract: | The modified toughened epoxy resin was prepared with using nano montmorillonite as materials by intercalation polymerization method. The effects of reaction temperature, reaction time, montmorillonite type and content on the elongation at break of the modified epoxy resin were investigated by orthogonal experiment. The results showed that reaction time had a great effect on elongation at break of the modified epoxy resin. When the reaction temperature was 70℃, reaction time was 2h, montmorillonite type was DK1 and content was 2%, the elongation at breaking of the modified epoxy resin was up to 12.11% and the impact strength was 13.61MPa. |
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| Keywords: | Epoxy resin nano montmorillonite intercalation polymerization toughening |
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