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Heat-transfer corrosion behaviour of cast Al alloy
Authors:Wei Zhou  Naing Naing Aung  Anil Choudhary  Mouhcine Kanouni
Affiliation:aPrecision Engineering and Nanotechnology Centre, School of Mechanical and Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore;bCiba Specialty Chemicals (India) Limited, Mumbai 400 053, India;cGlobal Applications Center, Ciba Specialty Chemicals Corporation, 540 White Plains Road, Tarrytown, NY 10591, USA
Abstract:Heat-transfer corrosion behaviour of an ISO 2379 cast Al alloy was studied in antifreeze radiator coolant under heat-rejecting condition. Extensive analyses of microstructures and corroded surfaces were carried out under the optical microscope, scanning electron microscope equipped with energy dispersive spectroscopy and X-ray diffractometer. Heat-rejecting condition led to a cavitation process and cavities were observed within the α-Al matrix. Crevice corrosion was predominant at oxygen depleted regions in heat-transfer corrosion cell. Al2Cu, Al15(Fe,Mn)3Si2 dendrites, Al4Cu2Mg8Si7 and Si phases served as the effective cathodes resulting microgalvanic corrosion at the anodic site of α-Al matrix.
Keywords:A. Alloy   A. Aluminum   B. SEM   C. Hot corrosion   C. Crevice corrosion
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