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316L不锈钢、690合金在氢氧化钠溶液中的电化学性能
引用本文:李成涛,李晓刚,程学群,董超芳.316L不锈钢、690合金在氢氧化钠溶液中的电化学性能[J].腐蚀与防护,2011(4):252-255,271.
作者姓名:李成涛  李晓刚  程学群  董超芳
作者单位:北京科技大学新材料技术研究院;腐蚀与防护教育部重点实验室;
基金项目:国家自然科学基金(No.50871020); 国家科技基础条件平台建设项目(No.2005DKA10400)资助
摘    要:采用动电位极化、电化学阻抗和电容测量等方法研究了316L、690合金在NaOH溶液中的电化学行为及生成钝化膜的半导体性质.在NaOH溶液中,316L不锈钢存在明显的钝化区间;316L不锈钢、690合金在NaOH溶液中电化学阻抗谱的阻抗模值相近.动电位电化学阻抗谱(DEIS)表明,随扫描电位正移,钝化膜的阻抗在测试溶液中...

关 键 词:316L不锈钢  690合金  电化学阻抗  Mott-Schottky曲线  平带电位(EFB)

Electrochemical Properties of 316L Stainless Steel and 690 Alloy in NaOH Solution
LI Cheng-tao,LI Xiao-gang.Electrochemical Properties of 316L Stainless Steel and 690 Alloy in NaOH Solution[J].Corrosion & Protection,2011(4):252-255,271.
Authors:LI Cheng-tao  LI Xiao-gang
Affiliation:LI Cheng-tao~(1,2),LI Xiao-gang~(1,CHENG Xue-qun~(1,DONG Chao-fang~(1,2) (1.Advanced Material & Technology Institute,University of Science & Technology Beijing,Beijing 100083,China,2.Key Laboratory of Corrosion and Protection of Ministry of Education of China,China)
Abstract:The electrochemical behaviors of passive film formed on 316L stainless steel and 690 alloy in NaOH solution were studied by potentiodynamic polarization,electrochemical impedance spectroscopy(EIS) and capacitance measurements.The results showed that there were significant differences between polarization curves of the two materials in NaOH solution.316L stainless steel had a wide passive anodic region from 100 mV to 900 mV in NaOH solution.The impedance value of the passive film on 316L stainless steel in N...
Keywords:316L stainless steel  690 alloy  EIS  Mott-Schottky plot  flat band potential(E_(FB))  
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