A one-step synthesis of protected functionalised titanocene dichlorides |
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| Affiliation: | 1. State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics, Sun Yat-sen University, Guangzhou, 510275, People''s Republic of China;2. State Key Laboratory of Optoelectronic Materials and Technologies, School of Electronics and Information Technology, Sun Yat-sen University, Guangzhou, 510275, People''s Republic of China;1. Department of Advanced Energy Engineering Science, Kyushu University, 6-1, Kasuga-koen, Kasuga, Fukuoka, 816-8580 Japan;2. Fusion Energy Research and Development Directorate, National Institutes for Quantum and Radiological Science and Technology, 2-166, Obuchi, Omotedate, Rokkasho-mura, Kamikita-gun, Aomori, 039-3212 Japan;1. Center for Single Particle Science and Engineering, University of Southern Denmark, Odense, Denmark;2. Department of Mechanical Engineering and Material Science, Duke University, Durham, North Carolina 27708;1. MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150090, China;2. State Key Lab of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China;1. Nanshan District Key Lab for Biopolymers and Safety Evaluation, College of Materials Science and Engineering and Department of Optoelectronic Engineering, Shenzhen University, Shenzhen, Guangdong, China;2. Chonbuk National University, School of Semiconductor and Chemical Engineering, Baekjero 567, Deokjin-gu, Jeonju, Jeonbuk 561–756, Republic of Korea;3. Department of Chemical Engineering, NED University of Engineering & Technology, University Road, Karachi 75270, Pakistan;4. Advanced Pharmaceutics and Drug Delivery Laboratory, Leslie Dan Faculty of Pharmacy, University of Toronto, 144 College Street, Ontario M5S 3M2, Canada;5. DSM Biomedical, 735 Pennsylvania Dr, Exton, PA 19341, USA;1. Department of Physical Chemistry and Materials Science, Budapest University of Technology and Economics, 1521 Budapest, Hungary;2. NMR Research Group, Institute of Organic Chemistry, Research Centre for Natural Sciences, Hungarian Academy of Sciences, 1525 Budapest, Hungary;3. Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, 1521 Budapest, Hungary |
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| Abstract: | We report a novel, high yield one-step synthesis of water stable and soluble titanocene dichloride dihydrochloride salts from the direct reaction of the neutral amino-substituted cyclopentadienes with TiCl4. The following novel complexes have been synthesised: C5H4(CH2)2N(CH2)5]2TiCl2 (5), [C5H4CH(CH2)4NMe]2TiCl2 (6), [C5H4(CH2)2N(CH2)5]2TiCl2·2HCl (7), [C5H4CH(CH2)4]2NMeTiCl2·2HCl (8), [C5H4(CH2)2N(CH2)5]2TiMe2 (9). |
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