The metal-chain complexes (X)[Os(CO)3(CNBut)]3Mn(CO)5 (X=Cl,Br, I) |
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| Affiliation: | 1. Department of Chemistry, Ferdowsi University of Mashhad, Mashhad 91775-1436, Islamic Republic of Iran;2. Departament de Química, Universitat de les Illes Balears, Crta. de Valldemossa km 7.5, 07122 Palma de Mallorca (Baleares), Spain;3. Department of Chemistry, Tulane University, New Orleans, LA 70118, USA |
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| Abstract: | In what is a new metal-chain forming reaction, (X)Os(CO)3(CNBut)]3Mn(CO)5 (X=Cl, Br, I) complexes have been prepared by the successive addition of Os(CO)4(CNBut) to Mn(CO)5(X) in hexane. The crystal structure of the iodo derivative reveals it to contain an approximately linear Os3 Mn chain of metal atoms. |
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