Kalman filtering of tunable diode laser spectrometer absorbance measurements

A recursive Kalman time-series filter was applied to absorbance measurements obtained with a tunable diode laser spectrometer. The spectrometer uses frequency modulation spectroscopy and a nearinfrared diode laser operating at 1.604 μm to monitor the CO(2)-vapor concentration in a 30-cm absorption cell. The Kalman filter enhanced the signal-to-noise ratio of the spectrometer by an order of magnitude when an absorbance of 6 × 10(-5) was monitored.