Effect of Si and Zr on the interdiffusion of U-Mo alloy and Al |
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Authors: | Jong Man Park Ho Jin Ryu Don Bae Lee Yeon Soo Kim |
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Affiliation: | a Korea Atomic Energy Research Institute, Daedeokdaero 1045, Yuseong, Daejeon 305-353, Republic of Korea b Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439, USA |
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Abstract: | We investigated the effect of Zr additions to U-Mo and Si additions to Al on interdiffusion between U-Mo and Al by employing diffusion couple tests. We examined the phase stability of the γ-heat-treated alloys by high-temperature annealing tests. Using X-ray diffraction, we observed that the γ-phase U-7Mo-Zr alloys with more than 2 wt% Zr decomposed faster than the U-7Mo alloys. The diffusion couples showed that a Zr addition to U-7Mo and the addition of Si in Al reduced the interaction layer growth rates. However, Zr additions to U-Mo are most effective in reducing the overall interdiffusion rates when combined with Si additions to Al. The decomposition of the metastable U-Mo γ-phase during the diffusion test appears to have a significant effect on the overall interdiffusion rates. |
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