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Modifications of carbon for polymer composites and nanocomposites
Authors:Nabarun Roy
Affiliation:a Rubber Technology Centre, Indian Institute of Technology, Kharagpur 721302, India
b Department of Chemistry, Indian Institute of Technology, Patna 800013, India
Abstract:The various forms of carbon used in composite preparation include mainly carbon-black, carbon nanotubes and nanofibers, graphite and fullerenes. This review presents a detailed literature survey on the various modifications of the carbon nanostructures for nanocomposite preparation focusing upon the works published in the last decade. The modifications of each form of carbon are considered, with a compilation of structure-property relationships of carbon-based polymer nanocomposites. Modifications in both bulk and surface modifications have been reviewed, with comparison of their mechanical, thermal, electrical and barrier properties. A synopsis of the applications of these advanced materials is presented, pointing out gaps to motivate potential research in this field.
Keywords:1  4-PDA  1  4-phenylenediamine  1H NMR  proton nuclear magnetic resonance  AFM  atomic force microscopy  AIG  alkali intercalated graphite  A-MWNT  amine functionalized MWNT  A-PPO  amine terminated linear polypropylene oxide  ASTM  American Society for Testing and Materials  ATRA  atom transfer radical addition  ATRP  atom transfer radical polymerization  BR  polybutadiene rubber  C11-MWNTS  undecyl-functionalized MWNTs  CB  carbon-black  C-MWNT  carboxylated MWNT  CNF  carbon nanofibers  CNT  carbon nanotube  CPP  chlorinated polypropylene  CR  chloroprene rubber  CRG  chemically reduced graphene  CRSG  chemically reduced sulfonated graphene  CSDPF  carbon-silica dual phase filler  CSM  chlorosulfonated polyethylene  CVD  chemically vapor deposition  DCC  N  N&prime  -dicyclohexylcarbodiimide  DFT  density functional theory  DGEBF  diglycidyl ether of bisphenol F  DMA  dynamic mechanical analysis  DMAc  dimethylacetamide  DMF  dimethyformamide  DPC-MWNT  diphenyl carbinol functionalized MWNT  DWNT  double-walled nanotube  ECA  electrically conductive adhesive  EDA  ethylenediamine  EEG  electrochemically exfoliated graphite  ENR  epoxidized natural rubber  EP  ethylene/propylene copolymer  EVA  ethylene vinyl acetate  FEF  fast extrusion furnace  FF  fine furnace  FM  flexural modulus (GPa)  FS  flexural strength (MPa)  GO  graphite oxide  GMA  glycidyl methacrylate  GPCNF  CNF graphitized at 2800   °  C  GPCNF-M  CNF subjected to graphitization and ball milling for 72   h  GPCNF-NA  CNF subjected to graphitization and 10% HNO3 treatment for 24   h  HAF  high abrasion furnace  HMDA  hexamethylenediamine  HPEKs  hyperbranched poly(etherketone)s  HRTEM  high resolution TEM  iGO  isocyanate-treated GO  iPP  isotactic polypropylene  IR  isoprene rubber  ISAF  intermediate super abrasion furnace  kGy  kilo gray  LCE  liquid-crystalline epoxy  LDPE  low density polyethylene  MAH  maleic anhydride  MEH-PPV  poly(2-methoxy-5-(2&prime  -ethyl-hexyloxy)-1  4-phenylene vinylene)  MPF  1-(4-methyl)-piperazinylfullerene  MW  molecular weight  MWD  molecular weight distribution  MWNT  multiwall carbon nanotube  MWNT-PSSA  poly(styrene sulfonic acid)-modified CNTs  NBR  nitrile rubber  NMR  nuclear magnetic resonance  NR  natural rubber  ODA  octadecylamine  O-MWNT  oxidized MWNT  OPV  oligophenylenevinylene  PA6  polyamide 6  PA 66  polyamide 6  6  PBS  poly(P-bromostyrene)  PBT  poly(butylene terephthalate)  PC  polycarbonate  PCBM  [6  6]-phenyl-C61-butyric acid methyl ester  PCL  polycaprolactum  PCNF  pristine CNF  PDI  polydispersity index  PDMS  polydimethylsiloxane  PEG  poly(ethylene glycol)  PEGMA  poly-(ethylene glycol) methyl ether methacrylate  PEN  poly(ethylene 2  6-naphthalate)  PEDOT  poly (3  4-ethylenedioxythiophene)  PEI  polyetherimide  PEO  polyethylene oxide  PET  polyethyleneterephthalate  PHR  parts per hundred parts rubber  PLA  polylactide  PLLA  l-lactide)" target="_blank">poly(l-lactide)  PMMA  poly(methyl methacrylate)  POSS  polyhedral oligomeric silsesquioxane  PP  polypropylene  PPA  poly(phenylacetylene)  PPB  poly(1-phenyl-1-butyne)  PPO  poly(2  6-dimethyl-1  4-phenylene oxide)  PS  polystyrene  PSF  polysulfone  PTC  positive temperature coefficient  PVAc  poly(vinyl acetate)  PVDF  poly(vinylidene fluoride)  PVK  poly(N-vinyl carbazole)  RAFT  reversible addition fragmentation chain transfer  RF  radio frequency  ROMP  ring-opening metathesis polymerization  SAF  super abrasion furnace  SAN  poly (styrene-ran-acrylonitrile)  SBR  styrene-butadiene rubber  SD-MWNT  silanized diphenyl carbinol functionalized MWNT  S-MWNT  silanized MWNT  SPEI  sulfonated polyetherimide  sPP  syndiotactic polypropylene  ss-DNA  single-stranded DNA  STM  scanning tunneling microscopy  STP  standard temperature and pressure  SWNT  single walled carbon nanotube  TC  thermal conductivity (W   m&minus    K&minus  1)  TCNEO  tetracyanoethylene oxide  Td5%  temperature of 5% of the total mass degradation  TEM  transmission electron microscopy  TEMPO  2  2  6  6-tetramethylpiperidinyl-1-oxy  TEMPOL  (4-hydroxyl-2  2  6  6-tetramethylpiperdinyloxyl)-terminated polystyrene  Tg  glass transition temperature  TGA  thermogravimetric analysis  THF  tetrahydrofuran  TMA  thermo-mechanical analyses  TMPTA  trimethylolpropane triacrylate  TPS  thermoplastic starch  TPU  thermoplastic polyurethane  TRG  thermally reduced graphite oxide  UHMWPE  ultra high molecular weight polyethylene  U-MWNT  unmodified MWNT  UV  ultraviolet  VGCF  vapor-grown carbon fibers  VGCNF  vapor-grown carbon nanofibers  XNBR  carboxylated NBR  XPS  X-ray photoelectron spectroscopy  XRD  X-ray diffraction  YM  Young's modulus (GPa)  β  field enhancement factor  ηc  carrier collection efficiency  ηe  energy conversion efficiency
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