| 酒石酸衍生手性荧光聚合物的合成及表征 |
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| 引用本文： | 杨新梅,黄立漳,戴平望,马杰,曾小玲,翁文. 酒石酸衍生手性荧光聚合物的合成及表征[J]. 陕西化工, 2014, 0(4): 629-631 |
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| 作者姓名： | 杨新梅 黄立漳 戴平望 马杰 曾小玲 翁文 |
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| 作者单位： | [1]闽南师范大学化学与环境科学系,福建漳州363000 [2]漳州市产品质量检验所,福建漳州363000 |
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| 基金项目： | 福建省自然科学基金杰出青年基金项目（2012J06005）; 福建省质量技术监督局项目（fjqi2013109） |
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| 摘 要： | 以对映纯酒石酸为碳源,在油酸介质中通过溶剂热法一步合成了荧光聚合物。制备的荧光聚合物水溶性好、发光稳定,未经钝化处理荧光量子产率可达4.02%。圆二色光谱分析表明,荧光聚合物具有手性特征。利用元素分析、光电子能谱、质谱等对手性荧光聚合物进行了表征。荧光聚合物的合成方法简单方便,易放大,产率高。
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| 关 键 词： | 荧光聚合物 酒石酸 圆二色 手性 |
Synthesis and characterization of fluorescent polymer with chirality property derived from tartaric acid |
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| YANG Xin-mei,HUANG Li-zhang,DAI Ping-wang,MA Jie,ZENG Xiao-ling,WENG Wen. Synthesis and characterization of fluorescent polymer with chirality property derived from tartaric acid[J]. Applied Chemical Industry, 2014, 0(4): 629-631 |
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| Authors: | YANG Xin-mei HUANG Li-zhang DAI Ping-wang MA Jie ZENG Xiao-ling WENG Wen |
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| Affiliation: | 1. Department of Chemistry and Environmental Science, Minnan Normal University, Zhangzhou 363000, China; 2. Zhangzhou Product Quality Supervision Institute,Zhangzhou 363000 ,China) |
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| Abstract: | A facile method was used to prepare fluorescent polymer by the pyrolysis of tartaric acid using oleic acid as the reaction media. The as-prepared fluorescent polymer had good water-solubility and stable photoluminescence. The quantum yield could reach 4. 02% without further passivation. The circular dichroism spectra showed that the obtained polymer still possessed chirality property. The product was characterized by element analysis,X-ray photoelectron spectroscopy,and mass spectrum. The method has some advantages such as easy to enlarge,easy to operate,high yield and simple post-processing. |
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| Keywords: | fluorescent polymer tartaric acid circular dichroism chirality |
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