Synthesis and properties of sandwiched films of epoxy resin and graphene/cellulose nanowhiskers paper |
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| Affiliation: | 1. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;2. University of Chinese Academy of Sciences, Beijing 100049, China;1. Department of Chemistry, School of Basic Sciences, Assam Kaziranga University, Koraikhowa, NH-7, Jorhat, 785006, Assam, India;2. Advanced Polymer and Nanomaterial Laboratory, Centre for Polymer Science and Technology, Department of Chemical Sciences, Tezpur University, Napaam, Tezpur, 784028, Assam, India;1. School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon 440-746, Republic of Korea;2. SKKU Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University, Suwon 440-746, Republic of Korea;3. Department of Electronic Materials Engineering, Kwangwoon University, Seoul 139-701, Republic of Korea |
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| Abstract: | Graphene (GN)-based composite paper containing 10 wt.% cellulose nanowhiskers (CNWs) exhibiting a tensile strength of 31.3 MPa and electrical conductivity of 16 800 S/m was prepared by ultrasonicating commercial GN powders in aqueous CNWs suspension. GN/CNWs freestanding paper was applied to prepare the sandwiched films by dip coating method. The sandwiched films showed enhanced tensile strength by over two times higher than the neat resins. The moduli of the sandwiched films were around 300 times of the pure resins due to the high content of GN/CNWs paper. The glass transition temperature of the sandwiched films increased from 51.2 °C to 57.1 °C for pure epoxy (E888) and SF (E888), and 49.8 °C to 64.8 °C for pure epoxy (650) and SF (650), respectively. The bare conductive GN/CNWs paper was well protected by the epoxy resin coating, which is promising in the application as anti-static materials, electromagnetic interference (EMI) shielding materials. |
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| Keywords: | A. Cellulose A. Graphene A. Nanocomposites B. Electrical properties |
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