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Characterization and properties of transparent cellulose nanowhiskers-based graphene nanoplatelets/multi-walled carbon nanotubes films
Affiliation:1. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, PR China;2. University of Chinese Academy of Sciences, Beijing 100049, PR China;1. Shenyang University of Chemical Technology, School of Materials Science and Technology, Shenyang 110142, PR China;2. Shenyang University of Chemical Technology, School of Chemical Engineering, Shenyang 110142, PR China;1. Department of Materials Science & Engineering, University of Ghana, Ghana;2. Institut des Matériaux Jean Rouxel (IMN), UMR 6502, CNRS, Université de Nantes, 2rue de La Houssinière, 44322, Nantes, Cedex 3, France;3. Department of Electrical Engineering, Newcastle University, Newcastle-Upon-Tyne, UK;1. School of Mechanical Engineering, Inner Mongolia University of Science & Technology, Baotou, Inner Mongolia 014010, PR China;2. Xi’an Research Institute of China Coal Technology & Engineering Group, Xi’an, Shaanxi Province 710077, PR China;1. Department of Computer Science, National Tsing Hua University, Hsinchu, Taiwan, ROC;2. College of Information Science & Electronic Engineering, Zhejiang University, Hangzhou, China;3. Department of Computer Science and Engineering, University of Notre Dame, Notre Dame, IN, USA
Abstract:Transparent cellulose nanowhiskers (CNW)/graphene (GN) and CNW/multi-wall carbon nanotube (MWCNT) films were obtained by ultrasonication assisted mechanically stirring followed by solvent casting methods. GN has more significant influence on the properties of CNW film than MWCNT does because GN exhibits strong interaction with CNW by its adsorption on the surface of GN. Thermal behaviors of CNW-based composite films were greatly affected by addition of GN or MWCNT. The melting peak and initial degradation temperature increase by 23.5 and 24 °C, and by 78 °C and 94 °C for the composite films containing 5 wt% MWCNT and 5 wt% GN, respectively. The composites show the contact angles of 61.9° for GN included film and 46.9° for MWCNT included film, which is higher than that of pure CNW film (42.8°).
Keywords:A. Hybrid  B. Thin films  C. Nano-structures  D. Thermal properties
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