Electrical conductivity and interlaminar shear strength enhancement of carbon fiber reinforced polymers through synergetic effect between graphene oxide and polyaniline |
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Affiliation: | 1. Department of Aeronautics and Astronautics, University of Tokyo, Bunkyo-ku, Tokyo, Japan;2. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China;3. Department of Materials Science and Technology, Tokyo University of Science, Tokyo, Japan;1. Department of Aeronautics and Astronautics, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan;2. Department of Organic Device Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa, Yamagata, 992-5810, Japan;1. Graduate Aerospace Laboratories, California Institute of Technology, United States;2. Arconic Fastening Systems and Rings, United States;1. Tecnalia, Paseo Mikeletegi 2, San Sebastián 20009, Spain;2. Airbus France, 316 Route de Bayonne, 31060 Toulouse, Cedex 09, France;3. Airbus Group Innovations, 12 Rue Pasteur, 92152 Suresnes, Cedex, France;1. School of Materials Science and Engineering, Shanghai University, Shanghai, 200444, China;2. Division of Advanced Nano-Materials, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou, 215123, China;3. Department of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing, 210094, China;1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;2. University of Chinese Academy of Sciences, Beijing 100190, China;3. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China |
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Abstract: | Utilizing synergetic effect of different ingredients is an important strategy to design new multi-functional composites. In this work, high-strength graphene oxide and conductive polyaniline were selected to dope into divinylbenzene to fabricate a new type carbon fiber reinforced polymer laminates, where a cooperative improvement of through-thickness electrical conductivity and interlaminar shear strength was observed. With addition of 15 wt% of PANI-GO at the optimized weight ratio of 60:1 in the CF/DVB-PANI-GO, 150% enhancement of the electrical conductivity compared to the CF/DVB-PANI, and 76% enhancement of the ILSS compared to the CF/DVB-GO were realized. Our laminates reach 66% in ILSS of that for the conventional CFRP made of epoxy, but the former features about 103 times higher AC conductivity. The mechanism for such a synergic enhancement for both electrical and mechanical performance was investigated by rheology measurement and scanning electron microscopy, where uniform 3-D network formed by PANI/GO has been clearly observed. |
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Keywords: | A Graphene A Polymer-matrix composites (PMCs) B Electrical properties B Mechanical properties |
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