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Comparison of the group V and VI transition metal carbides for methane dry reforming and thermodynamic prediction of their relative stabilities
Authors:Attila J Brungs  Andrew PE York  Malcolm LH Green
Affiliation:(1) Department of Chemical Engineering and Chemical Technology, Imperial College of Science, Technology and Medicine, Prince Consort Road, London, SW7 2BY, UK
Abstract:The DME‐SCR activity was suppressed upon exposure of a γ-alumina catalyst to SO2, in contrast to methanol‐SCR, which remains active at the same surface sulphate coverage. This difference in behaviour is attributed to the limited availability of surface methoxy, which may be regarded as a prerequisite for NOx- reduction over γ-alumina under lean conditions, in the case of dimethyl ether in the presence of SO2. This revised version was published online in July 2006 with corrections to the Cover Date.
Keywords:SO2            NO reduction  dimethyl ether            γ  -alumina
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