| 用过渡金属络合催化剂在水介质中引发烯烃单体的配位聚合 |
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| 引用本文： | 毕吉福,张学全,董为民,姜连升. 用过渡金属络合催化剂在水介质中引发烯烃单体的配位聚合[J]. 合成橡胶工业, 2007, 30(4): 316-319 |
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| 作者姓名： | 毕吉福 张学全 董为民 姜连升 |
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| 作者单位： | 中国科学院,长春应用化学研究所,吉林,长春,130022;中国科学院,长春应用化学研究所,吉林,长春,130022;中国科学院,长春应用化学研究所,吉林,长春,130022;中国科学院,长春应用化学研究所,吉林,长春,130022 |
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| 摘 要： | 介绍了乙烯、丁二烯和苯乙烯等单体在水介质中用过渡金属络合催化剂合成有规立构聚合物的研究进展,详细阐述了钴系催化剂在水介质中合成间同1,2-聚丁二烯的研究成果。
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| 关 键 词： | 水介质 烯烃单体 过渡金属络合催化剂 间同1 2-聚丁二烯 综迷 |
| 文章编号： | 1000-1255（2007）04-0316-04 |
| 修稿时间： | 2006-10-302007-06-12 |
Olefin coordination polymerization initiated by transitional metal complex catalysts in media of water |
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| Bi Jifu,Zhang Xuequan,Dong Weimin,Jiang Liansheng. Olefin coordination polymerization initiated by transitional metal complex catalysts in media of water[J]. China Synthetic Rubber Industry, 2007, 30(4): 316-319 |
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| Authors: | Bi Jifu Zhang Xuequan Dong Weimin Jiang Liansheng |
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| Affiliation: | Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China |
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| Abstract: | Research progress in olefin polymerization catalysed by the transitional metal complex in the media of water including ethylene,butadiene,styrene,etc.was reviewed with 16 references in order to synthesis stereo regular polymer.Study on the synthesis of syndiotactic 1,2-polybutadiene using the cobalt catalyst in water media was introduced in detail. |
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| Keywords: | media of water olefin monomer transitional metal complex catalyst syndiotactic 1 2-polybutadiene review |
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