Autothermal chemical looping reforming process of different fossil liquid fuels

The autothermal Chemical-Looping Reforming (a-CLR) is a process where syngas is produced with two main advantages; there are captured CO₂ emissions and the heat required for the syngas production is generated by the process itself. A Ni-based material is used as oxygen carrier circulating between two fluidized bed reactors: the fuel and air reactors. In this work, the auto-thermal conditions in a global H₂ production process, integrated by the a-CLR process and a Water Gas Shift reactor, using different liquid fossil fuels were theoretically determined. The hydrogen production per mol of carbon in the fuel was similar for all fossil fuels, taking a value of 2.2 at the optimal operating temperature (700 °C). In addition, the possibility of working at low temperature for a maximum H₂ production was experimentally demonstrated in a continuous 1 kW_th a-CLR unit.