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New controlling method for product distribution in Fischer-Tropsch synthesis reaction |
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| Authors: | Kaoru Fujimoto Li Fan Kyotaka Yoshii |
| Affiliation: | (1) Department of Synthetic Chemistry, Faculty of Engineering, The University of Tokyo, 113 Tokyo, Japan;(2) Ube Research and Development Laboratory, UBE Industries, Ltd., 755 Ube, Yamaguchi, Japan |
| Abstract: | Addition of a small amount of heavy 1-olefin into a supercritical-phase or liquid-phase FT reaction medium could significantly promote the carbon-chain growth and greatly enhance the selectivity of waxy products, with increased CO conversion while suppressing methane selectivity. The phenomenon was not observed in the gas-phase reaction. |
| Keywords: | Fischer-Tropsch synthesis olefin addition supercritical phase carbon chain transport effect |
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