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Sorption of 131I2 and CH3 131I from gas-water vapor medium with porous inorganic sorbents containing d elements
Authors:S A Kulyukhin  L V Mizina  N V Tanashchuk  I A Rumer  N A Konovalova  V V Sergeev
Affiliation:(1) Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia
Abstract:Sorption of 131I2 and CH3 131I from gas-water vapor medium on porous inorganic sorbents based on silica gel of the MSKG type, containing d elements, was studied. Sorbents containing Zn, Ni, Cu, and Co ammoniates show a low degree of recovery of 131I2 and CH3 131I from the gas-water vapor flow (less than 30%); their calcination at a temperature above 250°C does not noticeably affect the sorption power of the sorbent. The sorbents containing Zn, Ni, and Cu nitrates, both unmodified and modified, show a low degree of recovery of CH3 131I from the gas-water vapor medium (less than 1%). At the same time, whereas for unmodified sorbents the degree of recovery of 131I2 from the gas-water vapor phase does not exceed 70%, their modified analogs have higher degree of absorption of 131I2 (more than 99%), comparable with the similar data for Ag-containing sorbents based on silica gel of the MSKG type.
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