Sorption of 131I2 and CH3
131I from gas-water vapor medium with porous inorganic sorbents containing d elements |
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Authors: | S A Kulyukhin L V Mizina N V Tanashchuk I A Rumer N A Konovalova V V Sergeev |
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Affiliation: | (1) Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia |
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Abstract: | Sorption of 131I2 and CH3 131I from gas-water vapor medium on porous inorganic sorbents based on silica gel of the MSKG type, containing d elements, was studied. Sorbents containing Zn, Ni, Cu, and Co ammoniates show a low degree of recovery of 131I2 and CH3 131I from the gas-water vapor flow (less than 30%); their calcination at a temperature above 250°C does not noticeably affect the sorption power of the sorbent. The sorbents containing Zn, Ni, and Cu nitrates, both unmodified and modified, show a low degree of recovery of CH3 131I from the gas-water vapor medium (less than 1%). At the same time, whereas for unmodified sorbents the degree of recovery of 131I2 from the gas-water vapor phase does not exceed 70%, their modified analogs have higher degree of absorption of 131I2 (more than 99%), comparable with the similar data for Ag-containing sorbents based on silica gel of the MSKG type. |
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