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Bromate Formation during Ozonation of Bromide Containing Drinking Water- a Pilot Scale Study
Authors:Tiia Myllykangas  Tarja Nissinen  Terttu Vartiainen
Affiliation:1. National Public Health Institute, Division of Environmental Health, Laboratory of Chemistry , P.O. Box 95, FIN-70701, Kuopio, Finland;2. National Public Health Institute, Division of Environmental Health, Laboratory of Chemistry , P.O. Box 95, FIN-70701, Kuopio, Finland;3. University of Kuopio, Department of Environmental Sciences , P.O. Box 1627, FIN-70211, Kuopio, Finland
Abstract:The effect of bromide ion concentration, pH, temperature, alkalinity, and hydrogen peroxide content on bromate formation was studied. Increase in pH was found to give the greatest increase in bromate formation. Also increase in the ozonation temperature, bromide ion concentration and hydrogen peroxide content increased the observed bromate concentration. Only increased alkalinity decreased the bromate formation during the ozonation experiments. Bromate formation exceeded the EU limit value for bromate ion, 10 μg/l, when the initial bromide ion concentration was around 100 μg/l, except for the alkalinity of 1.4 mmol/1, when the bromate formation was 9.4 μg/l.
Keywords:Ozone  Bromate Ion  Bromide Ion Concentration  Ozonation  Pilot Scale Study  Drinking Water Treatment
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