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塑料浮选药剂
引用本文:王晖,顾帼华,邱冠周.塑料浮选药剂[J].高分子材料科学与工程,2003,19(2):20-23.
作者姓名:王晖  顾帼华  邱冠周
作者单位:中南大学化学化工学院,湖南,长沙,410083
基金项目:全国优秀博士学位论文作者专项资金资助 ( 2 0 0 145 )
摘    要:有关塑料浮选的润湿机理,主要存在由范德华色散力及氢键作用而导致的选择性物理吸附,由疏水相互作用和静电作用导致的物理吸附以及主要以静电作用为基础的物理吸附三种观点。目前用于塑料浮选的药剂,主要是木质素磺酸盐,单宁酸,明胶,白雀树皮汁,司盘,褐煤蜡,月桂醇,增塑剂DIDP,聚糖,水玻璃,醋酸纤维素等。

关 键 词:塑料浮选  低能表面  表面活性剂  润湿  浮选药剂  废旧塑料处理
文章编号:1000-7555(2003)02-0020-04
修稿时间:2002年4月29日

THE REAGENTS OF PLASTICS FLOTATION
WANG Hui,GU Guo-hua,QIU Guan-zhou.THE REAGENTS OF PLASTICS FLOTATION[J].Polymer Materials Science & Engineering,2003,19(2):20-23.
Authors:WANG Hui  GU Guo-hua  QIU Guan-zhou
Abstract:There are three points of view about the w etting mechanism in the flotation separation of plastics, namely (a) the adsorpt ion of reagents on plastics is mainly driven by physisorption, the interaction f orce include the dispersive van-der-waals force as well as hydrogen bondings, electrostatic interactions occur seldom because of the absence of a minimum amou nt of free charge carriers; (b) the interaction force include hydrophobic intera ctions and electrostatic forces, hydrogen bonding is not involved in the adsorpt ion on plastics; (c) the interaction is mainly driven by electrostatic forces un der the conditions of the presence of bivalent cations such as calcium. At prese nt, the reagents of plastics flotation include lignosulphonate, tannic acid, gel atine, quebracho, saponin, montan wax, lauryl alcohol, diisodecyl phthalate, sor bitan monolaurate, sodium silicate, acetate cellulose, etc.
Keywords:plastics flotation  low free energy surface  surfactant  w etting  flotation reagent
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