Superconductivity in the tetragonal phase of La1.9Bi0.1CuO4+δ annealed under high oxygen pressure |
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Authors: | Masatsune Kato Takaaki Aoki Takashi Noji Yasuhiro Ono Yoji Koike Tomoyuki Hikita Yoshitami Saito |
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Affiliation: | 1. Department of Applied Physics, Faculty of Engineering, Tohoku University, Aramaki Aoba, Aoba-ku, 980, Sendai, Japan
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Abstract: | We have investigated the relation between the crystal structure and superconductivity in La1.9Bi0.1CuO4+δ , in which the phase separation observed in La2CuO4+δ is suppressed. A phase diagram in theT?δ plane is given for La1.9Bi0.1CuO4+δ with excess oxygen. For very smallδ values, the crystal structure is orthorhombic, and an orthorhombic-tetragonal phase transition occurs markedly atδ ~ 0.03 in the measured temperature range between 13 and 293 K. Superconductivity is observed in the range of 0.04<δ<0.11. This is clear evidence thathigh-T c superconductivity also appears in the tetragonal phase. |
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