Anomalous photoemission threshold in high-T c oxide superconductor with Cs and K submonolayers

The photoemission threshold and photocurrent spectra were investigated for Bi₂Sr₂CaCu₂O₈ crystals with K or Cs submonolayer films. The different films of K or Cs were deposited on the Bi-O surface in the temperature range 80–250 K. We observed an appreciable (up to 0.3 eV) energy shift of the threshold and a strong modification of the photocurrent spectra for different temperatures and submonolayer coverages. The appropriate model of such a phenomena is based on a quasimetallic K or Cs clusters effect and additional 2D-polaronic effect.