| 高吸水性树脂丙烯酰胺-丙烯酸-对苯乙烯磺酸钠三元共聚物的合成 |
| |
| 引用本文： | 余巧玲,杨燕,张杰.高吸水性树脂丙烯酰胺-丙烯酸-对苯乙烯磺酸钠三元共聚物的合成[J].石化技术与应用,2012,30(3):221-223. |
| |
| 作者姓名： | 余巧玲 杨燕 张杰 |
| |
| 作者单位： | 1. 西南石油大学研究生院,四川成都,610500
2. 西南石油大学材料科学与工程学院,四川成都,610500 |
| |
| 摘 要： | 以丙烯酰胺(AM)、丙烯酸(AA)和对苯乙烯磺酸钠(SSS)为单体,过硫酸钾为引发剂,N,N'-亚甲基双丙烯酰胺为交联剂,采用溶液聚合法制备出AM - AA - SSS三元共聚物.结果表明,聚合最佳条件为:AA用量10 mL,AM用量3.3g,SSS用量0.5 g,引发剂用量0.040 g,交联剂用量0.010 g,反应温度60℃.在此条件下,试样的吸蒸馏水倍率为259g/g,吸盐水倍率为42 g/g.
|
| 关 键 词： | 丙烯酰胺 丙烯酸 对苯乙烯磺酸钠 溶液聚合 三元共聚物 吸水性树脂 吸水倍率 |
Synthesis of super absorbent resin acrylamide - acrylic acid - sodium p - styrene sulfonate terpolymer |
| |
| YU Qiao-ling
,
YANG Yan
,
ZHANG Jie.Synthesis of super absorbent resin acrylamide - acrylic acid - sodium p - styrene sulfonate terpolymer[J].Petrochemical Technology & Application,2012,30(3):221-223. |
| |
| Authors: | YU Qiao-ling YANG Yan ZHANG Jie |
| |
| Affiliation: | 1(1.Graduate School,Southwest Petroleum University, Chengdu 610500,China; 2.School of Materials Science and Engineering,Southwest Petroleum University,Chengdu 610500,China) |
| |
| Abstract: | Acrylamide(AM)-acrylic acid(AA)-sodium p-styrene sulfonate(SSS) terpolymer was synthesized by solution polymerization with AM,AA and SSS as monomers,potassium persulfate as initiator,N,N′-methylene bisacrylamide as crosslinking agent.The results showed that the optimum synthetic conditions were AA 10mL,AM 3.3g,SSS 0.5g,initiator 0.040g,crosslinking agent 0.010g,reaction temperature 60℃.Under these conditions,the water absorption rate of the polymer was 259g/g,the salt water absorption rate of the polymer was 42g/g. |
| |
| Keywords: | acrylamide acrylic acid sodium p-styrene sulfonate solution polymerization terpolymer absorbent resin water absorption rate |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
