| 反应条件对Cu-Ni/Al2O3催化剂乙炔选择加氢的影响 |
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| 引用本文： | 陈玉,刘琳,刘百军.反应条件对Cu-Ni/Al2O3催化剂乙炔选择加氢的影响[J].石化技术与应用,2012,30(6):497-500. |
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| 作者姓名： | 陈玉 刘琳 刘百军 |
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| 作者单位： | 中国石油大学(北京)化学工程学院 重质油国家重点实验室 中国石油天然气集团公司催化重点实验室,北京,102249 |
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| 摘 要： | 采用浸渍法制备出Cu-Ni/Al2O3催化剂。研究了催化剂还原温度及加氢反应条件对乙炔加氢反应的影响。结果表明,催化剂最佳还原温度为400℃。当最佳加氢反应条件为温度55℃,空速7 000 h-1,H2/C2H2(摩尔比)2.00时,乙炔转化率、乙烯选择性和收率分别为89.34%,84.48%,75.48%。
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| 关 键 词： | 乙炔 选择加氢 Cu-Ni/Al2O3催化剂 反应条件 |
Effect of reaction process conditions on selective hydrogenation of acetylene over Cu-Ni/Al2O3 catalyst |
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| CHEN Yu
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LIU Lin
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LIU Bai-jun.Effect of reaction process conditions on selective hydrogenation of acetylene over Cu-Ni/Al2O3 catalyst[J].Petrochemical Technology & Application,2012,30(6):497-500. |
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| Authors: | CHEN Yu LIU Lin LIU Bai-jun |
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| Affiliation: | CHEN Yu, LIU Lin, LIU Bai - jun (State Key Laboratory of Heavy Oil Processing, State Key Laboratory of Catalysis of CNPC, Faculty of Chemical Engineering, China University of Petroleum, Beijing 102249, China) |
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| Abstract: | Cu-Ni/Al2O3 catalyst was prepared by impregnation method. The influences of reduction temperature of the catalyst and hydrogenation reaction condition on the performance of hydrogenation of acetylene over Cu-Ni/Al2O3 catalyst were inves- tigated. The results showed that the acetylene conversion, ethylene selectivity and ethylene yield were 89.34% ,84.48% ,75.48% respectively under the optimum hydrogenation reaction conditions of temperature 55℃ , space speed 7 000 h-l , H2/C2H2 （mole ratio） 2.00. |
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| Keywords: | acetylene selective hydrogenation Cu-Ni/Al2O3 catalyst reaction condition |
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