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| 丙烯酸油酸丁酯压敏胶的制备和性能研究 | |
| 引用本文： | 梁文学,吴伟卿,邱学青.丙烯酸油酸丁酯压敏胶的制备和性能研究[J].化工新型材料,2009,37(12). |
| 作者姓名： | 梁文学 吴伟卿 邱学青 |
| 作者单位： | 1. 华南理工大学化工与化工学院,广东省绿色化学产品技术重点实验室,广州,510640;广州宏昌胶粘带厂,广州,510800 2. 广州宏昌胶粘带厂,广州,510800 3. 华南理工大学化工与化工学院,广东省绿色化学产品技术重点实验室,广州,510640 |
| 摘 要： | 利用植物油基环氧油酸丁酯(EBO)为原料,合成功能性高分子单体丙烯酸油酸丁酯(ABO).通过红外光谱和核磁共振图谱研究表明,ABO分子中具有明显的丙烯酸基的特征吸收峰.示差扫描量热仪测试ABO的玻璃化温度(Tg)为-84.5℃.适合ABO加成反应的催化剂为N,N二甲基苯胺.通过ABO和甲基丙烯酸甲酯单体聚合,制备出低粘、无残留的压敏胶. |
| 关 键 词： | 丙烯酸油酸丁酯 压敏胶 红外光谱 核磁共振 |
Preparation and properties of acrylic acid butyl oleate pressure sensitive adhesive |
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| Liang Wenxue,Wu Weiqing,Qiu Xueqing.Preparation and properties of acrylic acid butyl oleate pressure sensitive adhesive[J].New Chemical Materials,2009,37(12). | |
| Authors: | Liang Wenxue Wu Weiqing Qiu Xueqing |
| Abstract: | A novel monomer acrylate methyl oleate(ABO)capable of forming high molecular weight polymers was synthesized from a plant oil-based epoxidized methyl oleate(EBO), The analyses and characterization of ABO carried out with FTIR and ~1H-NMR spectrum exhibied that the acrylic acid group was in ABO. The DSC showed that the glass-transi-tion temperature (Tg) of ABO was -84.5℃. The influences of the initiators reaction time were investigated that N, N-dimethylaniline was a suitable catalyst synthesized ABO. It was found that the pressure sensitive adhesive made from co-polymer of ABO and methacrylate methyl ester could be low tack and strippable performance. |
| Keywords: | acrylic acid butyl oleate pressure sensitive adhesive FTIR ~1H-NMR |
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