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Phase Transformation and Optical Properties of Annealed Hydrothermally Synthesized ZnO/ZnCr2O4 Nanocomposites
Authors:Ashish Kumar  Tejendra Dixit  Iyamperumal A Palani  Pankaj R Sagdeo  Vipul Singh
Affiliation:1. Molecular and Nanoelectronics Research Group (MNRG), Department of Electrical Engineering, IIT Indore, Indore, Madhya Pradesh, India;2. Mechatronics and Instrumentation Lab, Department of Mechanical Engineering, IIT Indore, Indore, Madhya Pradesh, India;3. Centre of Material Science and Engineering, IIT Indore, Indore, Madhya Pradesh, India;4. Department of Physics, IIT Indore, Indore, Madhya Pradesh, India
Abstract:The effect of postgrowth thermal annealing on ZnO/ZnCr2O4 nanocomposites synthesized by hydrothermal method has been thoroughly investigated. XRD data have clearly revealed the transformation of spinel cubic phase of ZnCr2O4 to wurtzite phase ZnO and indicated the incorporation of Cr in ZnO lattice with annealing at high temperatures. Photoluminescence spectra have shown a strong dependence of emission on annealing temperatures. This work demonstrated the unique and simple route to fabricate Cr‐doped ZnO and tuning of the luminescence with annealing temperature. Thus, the work has immense potential for optoelectronic and photovoltaic applications.
Keywords:annealing  composites  phase transformation  zinc oxide
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