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Influence of triethanolamine on the hydration characteristics of tricalcium silicate
Authors:V S Ramachandran
Abstract:The hydration characteristics of 3CaO.SiO2 or β2CaO.SiO2 are studied by an addition of 0.0, 0.1, 0.5 or 1.0% triethanolamine. The amount of Ca(OH)2 found at 1, 3, 7 or 28 days was in the order C3S + 0% TEA > C3S +0.1% TEA > C3S + 0.5% TEA > C3S+1.0% TEA, irrespective of whether lime was estimated by X-ray, DTA, TGA or chemical analysis. The rate of hydration, in terms of the disappearance of 3CaO.SiO2, showed that hydration proceeded faster in the presence of TEA after 1 day. Additions of TEA increase the induction period, promote the formation of a C-S-H with higher CaO/SiO2 ratio, increase the formation of non-crystalline Ca(OH)2 and enhance the surface area of the hydrated silicate product.
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